Carbon-carbon bond making reactions

  1. The Corey-House Reaction - makes alkanes

  2. The Diels-Alder Reaction

  3. Reaction of acetylide ions with haloalkanes

  4. RX + -CºC- ® -CºC-R

  5. Friedel-Crafts alkylation

  6. ArH + RX/AlCl3 ® ArR

  7. Friedel-Crafts acylation

  8. ArH + RCOCl/AlCl3 ® ArCOR

  9. Reaction of Grignard reagents with aldehydes, carbon dioxide, esters, ethylene oxide and ketones

    1. with methanal (formaldehyde)
    2. with other aldehydes
    3. with ketones
    4. with ethylene oxide
    5. with esters
    6. with carbon dioxide

  10. Reaction of cyanide with haloalkanes

  11. RX + CN- ® RCN

  12. Reaction of acid chlorides with lithium cuprates

  13. Reaction of aldehydes and ketones with cyanide

  14. The Wittig reaction

  15. The Aldol condensation

  16. Alkylation

  17.  

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This page is maintained by Dr. Ed Blackburn (Ed.Blackburn@UAlberta.CA), course instructor.

Updated August 23, 2002