
Carbon-carbon bond making reactions

-
The Corey-House Reaction -
makes alkanes
-
The Diels-Alder Reaction
-
Reaction of acetylide ions
with haloalkanes
RX + -CºC-
® -CºC-R
-
Friedel-Crafts alkylation
ArH + RX/AlCl3
® ArR
-
Friedel-Crafts acylation
ArH + RCOCl/AlCl3
®
ArCOR
-
Reaction of Grignard reagents
with aldehydes, carbon dioxide, esters, ethylene oxide and ketones
- with methanal (formaldehyde)
- with other aldehydes
- with ketones
- with ethylene oxide
- with esters
- with carbon dioxide
-
Reaction of cyanide with
haloalkanes
RX + CN-
® RCN
-
Reaction of acid chlorides
with lithium cuprates
-
Reaction of aldehydes and
ketones with cyanide
-
The Wittig reaction
-
The Aldol condensation
-
Alkylation


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| Faculté Saint-Jean |
University of Alberta |
Chemistry Department

This page is maintained by Dr. Ed
Blackburn (Ed.Blackburn@UAlberta.CA),
course instructor.
Updated August 23, 2002